Temperature-dependent elastic constants of thorium dioxide probed using time-domain Brillouin scattering

نویسندگان

چکیده

We report the adiabatic elastic constants of single-crystal thorium dioxide over a temperature range 77–350 K. Time-domain Brillouin scattering, an all-optical, non-contact picosecond ultrasonic technique, is used to generate and detect coherent acoustic phonons that propagate in bulk perpendicular surface crystal. These lattice vibrations have been monitored two hydrothermally grown samples along (100) (311) crystallographic directions. The three independent cubic crystal (C11, C12, C44) are determined from measured velocities. longitudinal wave orientation provided direct measurement C11. Measurement C44 C12 was achieved by enhancing intensity quasi-shear mode oriented adjusting polarization angle relative axes. find magnitude softening be ∼2.5% range. Good agreement found between with previously reported values at room temperature, temperature-dependent modulus calculated values. semi-empirical models capturing anharmonicity adequately reproduce observed trend. also determine Grüneisen parameter experimentally derived volumetric thermal expansion coefficient heat capacity. This work presents measurements elasticity cryogenic provides basis for testing ab initio theoretical evaluating impact on thermophysical properties.

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ژورنال

عنوان ژورنال: Journal of Applied Physics

سال: 2023

ISSN: ['1089-7550', '0021-8979', '1520-8850']

DOI: https://doi.org/10.1063/5.0148866